Research

  • Research Projects
    • Clathrate Hydrate Formation Kinetics
    • Critical Casimir Effect in Liquid Helium
    • Anomalous Radiated Heat Transfer
    • Cryogenic characterization of MEMS
    • Pulsed Laser Deposition
    • Liquid lenses
    • Wetting on Weak and Intermediate Strength Substrates
    • Weak Substrates
    • Cesium deposition
    • Prewetting transitions
    • Superfluidity
    • Ellipsometry
    • Superfluid drop dynamics: Pinch-off
    • Room temperature drop dynamics: Pinch-off
    • Superfluid drop dynamics: Sliding droplets
    • Dynamic Friction
    • Classical fluid drop & contact line dynamics: Pinch-off in mercury
    • Dissipation in oscillating drops
    • Nucleation in cesiated containers
    • Superfluid fog

 

  • Clathrate Hydrate Formation Kinects
    • Clathrate Hydrates (or simply hydrates) are ice-like crystalline compounds that form naturally in the deep ocean and can be artificially synthesized. The industrial applications of hydrate research are vast and include such fields as alternative energy, global warming, water desalination, and gas storage.
    • In all applications understanding the kinetics of hydrate formation is of critical importance. Whether you are trying to maximize the formation rate in a water desalination plant or predict where to find hydrate deposits on the ocean floor, understanding hydrate formation kinetics is crucial.
    • We currently study two very intriguing hydrate systems.
      • Hydrate formation in the presence of surfactants: Certain surfactants can enhance hydrate formation rates by as much as 100x. The mechanism by which this occurs is unknown. We are currently working on shedding light on this mechanism and are in the process of writing up some very promising results.
      • Hydrate formation from saltwater: One fascinating application for hydrates is water desalination. As hydrates form the crystal excludes the salt, offering a mechanism for turning salt water into freshwater. However, forming hydrates from saltwater is much more difficult than forming hydrates from freshwater. In addition, the surfactants that work wonders in fresh water (enhancing growth rates 100x) are rendered ineffective by the salt. We have discovered some new promising additives that can significantly enhance hydrate growth in salt water.
      • Below: Sequential pictures showing the formation of a Methane Hydrate grown at 275K from a mixture of liquid water and sodium dodecyl sulfate.growth_progress_gray

 

  • Critical Casimir Effect in Liquid Helium
    • This effect is distinct from the more commonly discussed Casimir Effect which occurs as a result of vacuum fluctuations. Instead in this effect a force between two plates can be observed due to fluctuations in density in a material near the a second order phase transition.
    • The second order phase transition we are interested in is that between fluid and superfluid helium-4 which occurs at around 2K. The forces associated with this effect are vanishingly small, on the order of pico newtons.
    • The tiny forces and low temperatures make experimental design a rigorous challenge. This necessitates much trial and error to develop novel techniques.

 

  • Anomalous Radiated Heat Transfer
    • For separation distances as large as our solar system or as small as your household toaster the theory describing radiated heat transfer remains unchanged. Specifically the flow of radiated heat between two objects is independent of their separation distance.
    • However, over distances on the order of the thermal wavelength (less than one micron) the flow of radiated heat between certain materials begins to drastically increase.
    • Materials such as glass can support surface plasmon resonances in the infrared range. These resonances create evanescent waves which can drastically enhance heat flow over tiny distances.
    • We have designed an apparatus for measuring this phenomenon. We use it to probe the nature of this effect in common materials such as glass and sapphire and hope to branch out into exotic materials such as super conductors.

 

  • Cryogenic characterization of MEMS
    • Micro-electro-mechanical systems (MEMS) are mechanical devices built on silicon wafers at the micron scale. These devices have been in existence for almost as long as the integrated circuits which are now found in computers. However, due to the complexity and difficulty in design and fabrication, as well as the strong sensitivity (sometimes oversensitivity) of the devices, they have not become as widely used. They are currently employed in a number of applications as pressure sensors and accelerometers, to name a few. In order for more complex MEMS devices to become widely used, the behavior of these devices must be studied. We are studying a MEMS resonator in air and vacuum from room temperature to 6K. Specifically, we intend to study how wear, stiction, and resonance change while changing pressure and temperature.

      There is clearly a strong difference between the resonance curves for the MEMS device
      in air and under vacuum at room temperature. The quality factor, Q, of the device
      changes from 5 in air to 40,000 at 5×10-6 Torr.

 

  • Pulsed Laser Deposition
    • Preparing clean, uniform surfaces is difficult at cryogenic temperatures. In the past we have utilized thermal evaporation where a small container of Cesium or other metal is heated to 400K or above in a 4K environment. The metal is evaporated onto a quartz crystal microbalance (QCM). This method has two main difficulties; it becomes difficult to control how much material is placed on the QCM because of heating effects and this method adds a lot of heat to our cold system. To solve these problems we have developed another deposition method called Pulsed Laser Deposition (PLD). In this setup we utilize a Nd:YAG laser set to its second harmonic, 532nm light. This laser light is pulsed and has a pulse width of 10 ns. The light is brought into the cell and strikes a cold target. The local target area is heated up to thousands of degrees and material flies off the surface. A QCM is placed perpendicular to the surface of the target, as seen below, and the material is deposited onto the QCM.

      This method has the benefits of low heating and a great deal of control. We have sublayer deposition control with this setup.

 

  • Liquid Lenses
    • Pinch-off in conventional 3D droplets and bubbles have been of considerable recent interest. In 3D, pinch-off is driven by surface tension, and various flow regimes have been observed which depend on the viscosity and density ratios of the interior and exterior fluids. In contrast, 2D line tension lone can not drive a film to break apart. Liquid lenses provide an interesting intermediate case in which surface tensions are small and the geometry approaches 2 dimensions. We have developed an experimental system to reproducibly observe pinch-off in hydrocarbon liquid lenses. The shape of the pinch region is qualitatively different than that in 3D, and involves a hierarchy of multiple spontaneous singularities and satellite lenses. High-speed video will be shown which illustrates these phenomena.
    • Video: Liquid decane pinch-off on the surface of water                See the video

 

  • Wetting on Weak and Intermediate Strength Substrates              
    • What is wetting? If two coexisting phases, A and B, are in a container,
      the walls of the container will prefer either A or B. The preferred phase is said to wet the wall. The preference is quantitatively determined by the size and sign of the surface free energies in the problem:

      If , then B wets the wall.The surface free energies depend on temperature and other variables, and the inequality can be reversed as these variables are changed. In other words, as the temperature is varied, the system can change its mind about which phase it prefers. This is a wetting transition.Although the word “wetting” implies liquids, the physics is very general and applies to systems as varied as binary liquid mixtures, magnetic phases, and superconductors. The main idea is that even when bulk phases have exactly the same free energy and coexist, the surface breaks the symmetry and the phases and phase transitions that occur on the surface can be very different than in the bulk. These differences give rise to phenomena such as prewetting, and affect processes such as droplet formation, contact angles & contact angle hysteresis, nucleation, and flow which we investigate in our lab.

 

  • Weak Substrates
    • As noted above, wetting is the competition of phases for access to the wall.
      The competition is interesting when it is closely matched. One way to characterize the competition is interaction strengths. For example, if the
      interaction between particles in a liquid is stronger than the interaction between the liquid molecules and the wall, the liquid does not wet, and beads up on the surface in the form of a droplet with a finite contact angle.Liquid helium is a particularly weakly-interacting system. Since the interaction of helium with almost anything else is stronger than the helium-helium interaction, liquid helium was thought to wet everything. It was therefore surprising when Cheng, Cole, Saam, and Treiner predicted that helium would not wet cesium. The basic reason for this is that electrons are very weakly bound to cesium, so an electron cloud extends unusually far from a cesium surface; this cloud prevents the helium from getting very close to the surface to take advantage of the van der Waals well.

 

  • Cesium Deposition
    • Cesium is so reactive that it burns spontaneously in air. Our lab has developed the technology to fabricate clean, high quality cesium surfaces and has used them for a number of novel experiments with helium. Our method of making cesium films is to evaporate the elemental metal from a glass ampule. Cesium evaporates nicely at about 50ºC. Cleanliness is ensured by keeping the rest of the apparatus at 4 K.

 

  • Prewetting transitions
    • One method of monitoring the state of the surface is to use a quartz crystal
      microbalance (QCM)
      . We used QCMs coated with about 100 layers of cesium to investigate the surface phase diagram of 4He on Cs. The system shows a wetting transition at about 2 K and is the first experimental system to show a prewetting line. Prewetting is a first-order phase transition that separates thick and thin films, and is roughly analagous to a surface liquid-vapor transition.

      We have used this type of system to investigate wetting transitions in 3He,
      and in 4He-3He mixtures.

 

  • Superfluidity
    • Another focus of our interest is in the relationship between wetting and superfluidity. Superfluidity in thin helium films is a field which has been intensely studied. It is the classical example of a Kosterlitz-Thouless phase transition. It is particularly interesting on weak substrates because the film has 4 choices: It can be super or normal, thin or thick. Bulk cesium is so weak that liquid helium forms a superfluid film on it only very near the bulk lambda point. We have made intermediate strength substrates by using extremely thin cesium films or by using lighter alkali metals such as rubidium, potassium, and sodium.On both rubidium and thin cesium, we find that the so-called universal signatures of the Kosterlitz-Thouless transition are not observed.One reason for this non-universal behavior may be that localized solid-like layer of helium (Bose glass) at the interface with a conventional substrate is absent for intermediate strength substrates. In other words, on conventional substrate materials, superfluids interact with the solid wall through a solid He layer, while in weak substrates, the superfluid is in direct contact with the wall.Mechanical oscillators in general and QCMs in particular have been the tool of choice to study superfluid onset in thin films. The signature of superfluidity is an apparent decoupling of mass when the superfluid fraction is no longer viscously clamped to the motion of the substrate. On a weak substrate, however, an apparent decoupling of mass can be due to either superfluid onset or prewetting, and QCMs can not distinguish between the two possibilities, since they only measure the normal fraction. To disentangle the effects of wetting and superfluidity, we need a probe of the total (super + normal) coverage.

 

  • Ellipsometry
    • After assessing several possible techniques, we have decided on an ellipsometric detection scheme. Briefly, an ellipsometer measures the rotation in the polarization of light due to the adsorption of a thin film. More details. This
      project is technically challenging because the small optical index of helium (n = 1.03) produces very small polarization changes, and these can easily be swamped by temperature dependent birefringence in the many windows that are required in an optical cryostat. We have solved these problems and made ellipsometric measurements of helium films with sub-monolayer resolution at 1.5 K.
      Ellipsometric Study of Superfluid Onset in Thin Liquid 4He Films

 

  • Superfluid Drop Dynamics
    • Pinch-off  top
      When a piece of fluid separates into two droplets, there is a final instant at which the new droplet is born. The fluid flows that produce the separation are governed by highly nonlinear differential equations that have so-called spontaneous singularities. The flows are a competition between surface tension forces, which try to squeeze the fluid into two, and intertia and
      viscosity, which resists this.
      A superfluid droplet pinch-off: Compare this image to this one, taken a moment earlier.

This competition leads to universal icicle-like shapes in the fluid flow which are very beautiful. We have investigated the pinch-off process using superfluid helium to look for effects of viscosity and possible unusual superfluid phenomena. We have studied superfluid pinch-off using 5µs exposure flash photography and 1000 frame-per-second video.
See the video
Superfluid Drops: Dynamics of Pinch-Off and Sliding Motion


 

  • Room Temperature Drop Dynamics
    • Pinch-off
      We are also investigating pinch-off in droplets and bubbles at room temperature. We are searching for a similar categorization of pinch-off behavior based on the viscosities and densities of the inner and outer fluids. Interesting phenomena have been observed while studying these regimes.The videos below were made in a horizontal orientation. Refer to the figure below.
      Video 1: Air bubbling through glycerin. The regime where the viscosity of the inner fluid (air) is about 100,000 times smaller than the outer fluid.

      See the video
      Video 2: Water bubbling through heavy syrup. The regime where the viscosity of the inner fluid (water) is about 13,000 times smaller than the outer fluid.

      See the video
      Video 3: Air bubbling through water. The regime where the viscosity of the inner fluid (air) is about 1,000 times smaller than the outer fluid.

      See the video

 

  • Sliding droplets
    • This video shows superfluid Helium-4 at 1.5K dripping off the capillary and landing on a cesiated plate inclined at 21.5º from the horizontal. This angle is sufficiently steep so that pinning forces are immediately overcome and the drop begins to slide downhill. Remarkably, this measured acceleration amounts to approximately 20% of the predicted gravitational acceleration.

                                                           See the video


 

  • Dynamic friction in flow of droplets down an inclined plane
    • The discovery of weak substrates which are not wet by helium opens up new questions in superfluid dynamics. Conventional superfluid dynamics had no need to consider the motion of a superfluid boundary, because the superfluid immediately spread to wet all surfaces. On cesium substrates, drops of superfluid can be formed which have an edge where superfluidity stops. The first observation of these drops was reported in Superfluid drops on a solid surface. The drops of superfluid behave in a counter-intuitive fashion: although the fluid has no viscosity, the drops are very “sticky.” When superfluid is poured onto a cesiated inclined plane, it does not simply roll downhill. Rather, it will ball-up and resist flow until a critical mass is reached. Apparently the contact line is strongly pinned. This is surprising because the surfaces are formed in ultra-high vacuum, are mirror-like, and show sharp steps in the prewetting transition which can be observed on the same surfaces. We have measured the contact line hysteresis for 4He on Cs.There are strong pinning forces which prevent a drop from starting to move, but what happens when it finally does move? Is there an effective frictional force between the fluid and the plate? We have recently investigated this issue using high-speed video of flowing drops. We find that superfluid drops have an almost constant acceleration, but it is about 1/5 of the free-fall value of .

 

  • Classical fluid drop and contact line dynamics
    • Pinch-off in mercury
      Most experiments to investigate pinch-off have used optical images to look at the minimum neck diameter. We have used this technique to look at superfluid pinch- off. Optical techniques can follow the power law singularity predicted by fluid mechanics only down to optical wavelengths, but they should continue to much smaller length scales. We have developed an electrical technique based on measuring the resistance of a pinching column of liquid mercury with a high-speed digital oscilloscope. Using this technique, we can follow the dynamics of pinch-off to within a few nanoseconds of the singularity.

 

 


  • Dissipation in oscillating drops
    • Our experience with dissipation of superfluid drops suggests that contact line motion contributes to dissipation in an important but incompletely understood way. Even for a classical liquid, the dissipation of a moving drop cannot be computed directly from the Navier-Stokes equations. Attempts to do this run into non-convergent integrals and predict infinite dissipation. The standard way out is to invoke a slip length. We have developed a method based on monitoring the motion of a drop using a split diode detector to measure the mechanical Q of a liquid drop on a plate. We are investigating the effect of viscosity, contact angle, and vibration amplitude on the Q graph.

 

  • Superfluid Fog: Nucleation of supersaturated vapor in an evaporating liquid
    • A liquid coexisting with its vapor in a container with a temperature gradient will transfer heat and mass from the hot end to the cold end via evaporation and condensation. A careful analysis of this non-equilibrium process leads to some surprising and non-intuitive predictions: very larger temperature jumps develop near the liquid-vapor interfaces, and it is possible for the temperature in the vapor to be inverted so that the temperature near the hot evaporating fluid is actually colder than it is near the cold end where the fluid condenses. This effect is a clear prediction of non-equilibrium thermodynamics and has been seen in computer simulations but has never been observed in conventional fluids due to the difficulties in making the measurements. In the liquid helium system, the effects are so strong that with a modest evaporative flux, the gas in the interior can be driven into a supercooled metastable state. When the supercooling becomes sufficiently strong, the vapor undergoes homogeneous nucleation and forms a dense fog, which we have recently documented with video microscopy in our optical dewar.
      Supercooling Helium Vapor: Nucleation and Fog Formation induced by Strong
      Evaporation

      See the video